Silicon prepared by electro-reduction in molten salts as new energy materials
نویسندگان
چکیده
منابع مشابه
Polarography in Molten Salts
TYPES OF MELTS From the practical viewpoint, melts may be classified according to melting points which may limit the available techniques. The lowest melting, with working temperatures up to 250°, are typified by the LiNO3—NaNO3— KNO3 eutectic, NaNO3—KNO3 eutectic, LiClO4, and ammonium formate. With these solvents it is possible to use the dropping mercury electrode, or hanging mercury drop ele...
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For the first time we present the synthesis of CeO(2)/Si(O)C core-shell particles prepared by the miniemulsion technique. The Si(O)C core was obtained by means of a polycarbosilane precursor (SMP10), which was subsequently functionalized with ceria and pyrolyzed to the ceramic. The size of these particles could easily be adjusted by varying the surfactants and the surfactant concentration, or b...
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The factors which distinguish molten salts from other non-aqueous solvents are described and the range of systems available outlined. Some illustrative examples of the various classes of reactions carried out in molten salts are then given. These include the exchange of halides and pseudohalides in organic and inorganic compounds, organic chlorinations, eliminations and rearrangements, a consid...
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The electrochemical deposition and re-oxidation of solid carbon were studied in CO3(2-) ion-containing molten salts (e.g. CaCl2-CaCO3-LiCl-KCl and Li2CO3-K2CO3) at temperatures between 500 and 800 °C under Ar, CO2 or N2-CO2 atmospheres. The electrode reactions were investigated by thermodynamic analysis, cyclic voltammetry and chronopotentiometry in a three-electrode cell under various conditio...
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The work on molten salts and isotope separation performed over the years at Université Pierre et Marie Curie and at Collège de France is critically reviewed. This research, closely related to A. Klemm’s pioneering contributions, leads among other things to the discovery of the effect now called the ‘Chemla effect’, after the late Professor Marius Chemla. These studies of ionic motions in melts,...
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ژورنال
عنوان ژورنال: Journal of Energy Chemistry
سال: 2020
ISSN: 2095-4956
DOI: 10.1016/j.jechem.2019.11.005